It's probably because the acrylic resin in the formula has dried in the nozzle mechanism. See if you can remove the dried residue with warm soapy water and a stiff bottle brush, and try to give the nozzle a wash out after each use to stop it happening again.
No, Liquitex Palette Wetting Spray is designed to be used exclusively with acrylic paints.
Liquitex Palette Wetting Spray will keep your acrylic paints workable for longer and extend their open time.
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